Catalytic Asymmetric Synthesis of C-Chiral Phosphonates

被引：15
作者：
Kolodiazhna, Anastasy O. [1 ]
Kolodiazhnyi, Oleg, I [1 ]
机构：
[1] NAS Ukraine, VP Kukhar Inst Bioorgan Chem & Petrochem, Murmanska St 1, UA-02094 Kiev, Ukraine
来源：
SYMMETRY-BASEL | 2022年 / 14卷 / 09期
关键词：
C-chiral phosphonates; metal complex catalysis; organocatalysis; phospha-aldol reaction; phospha-Mannich reaction; phospha-Michael reaction; asymmetric hydrogenation; asymmetric reduction; ORGANOCATALYTIC CONJUGATE ADDITION; ALPHA-HYDROXY PHOSPHONATES; PHOSPHA-MICHAEL REACTION; HIGHLY ENANTIOSELECTIVE HYDROPHOSPHONYLATION; AMINOPHOSPHONIC ACID-DERIVATIVES; ABRAMOV-TYPE PHOSPHONYLATION; ENOL ESTER PHOSPHONATES; BOND FORMATION; ALPHA; BETA-UNSATURATED PHOSPHONATES; DIPHENYL PHOSPHITE;
D O I：
10.3390/sym14091758
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
The current review is devoted to the achievements in the development of methods for the catalytic asymmetric synthesis of phosphonates containing a chiral center in the side chain. C-chiral phosphonates are widely represented among natural compounds with various biological activities as insecticides, herbicides, antibiotics, and bioregulators. Synthetic representatives of this class have found practical application as biologically active compounds. The review summarizes methods of asymmetric metal complex catalysis and organocatalysis as applied to such reactions as phospha-aldol reaction, two-component and three-component phospha-Mannich reaction, phospha-Michael reaction, as well as hydrogenation of unsaturated phosphonates and phosphine oxides, ketophosphonates, and iminophosphonates. Methods for the asymmetric hydride reduction of C=X phosphonates (X=O, S, NR) are also discussed in detail. The review presents updated literature reports, as well as original research by the author.
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页数：56
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