Constructing one-dimensional mesoporous carbon nanofibers loaded with NaTi2(PO4)3 nanodots as novel anodes for sodium energy storage

被引:163
作者
Huang, Zan [1 ]
Luo, Peifang [2 ]
Wu, Qibao [3 ]
Zheng, Honghong [1 ]
机构
[1] Guangzhou Maritime Univ, Sch Naval Architecture & Ocean Engn, Guangzhou 510725, Guangdong, Peoples R China
[2] Guangzhou Maritime Univ, Fdn Dept, Guangzhou 510725, Guangdong, Peoples R China
[3] Shenzhen Inst Informat Technol, Sch Intelligent Mfg & Equipment, Shenzhen 518172, Peoples R China
关键词
Sodium-ion batteries; Superior high-rate performance; NaTi2(PO4)(3) dots; Mesoporous nanofibers; DOPED GRAPHENE SHEETS; PERFORMANCE; NANOCRYSTALS; COMPOSITE; MOS2;
D O I
10.1016/j.jpcs.2021.110479
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this research, the novel one-dimensional mesoporous NaTi2(PO4)3@C fibers (abbreviated as C-NTP-1D) are synthesized via an electrospinning method to promote the rate capability of pristine NaTi2(PO4)3 (NTP). The electrochemical properties, crystal structure and morphology for the resulted fibers have been explored by various electrochemical testing techniques, XRD, XPS, Raman spectroscopy, SEM as well as TEM. Benefiting from the designed mesoporous structure, the C-NTP-1D anode displays superior electrochemical properties. The specific capacities of 130.1 and 117.7 mAh g-1 is achieved at 0.1 and 2 C, and the C-NTP-1D presents the high capability of 89.1 mAh g-1 at 10 C following 500-cycle spans. Therefore, the designed mesoporous C-NTP-1D nanofibers can find potential applications as novel electrode for sodium-ion batteries.
引用
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页数:7
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