Crystal structure and physicochemical properties of new copper(II) complexes with 3,5-di(tert-butyl)salicylaldehyde acylhydrazone

被引:0
|
作者
Tupolova, YP
Lukov, VV
Kogan, VA
Popov, LD
Tkachev, VV
Chekhlov, AN
机构
[1] Rostov Don State Univ, Rostov Na Donu 344104, Russia
[2] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Oblast, Russia
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中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A series of new complexes was synthesized from copper(II) nitrate or perchlorate and acylhydrazones of salicylaldehyde derivatives with bulky tert-butyl substituents. It was shown that both the structural features of the ligands and the nature of acido ligands determined the structure and properties of the isolated complexes. The structure of the metal chelate synthesized by the reaction of copper nitrate with a ligand system obtained from hexanohydrazide, was determined by X-ray crystallography.
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页码:1629 / 1634
页数:6
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