Cymantrene- and Ferrocene-Based Complexes with Perfluorinated Bridging Moieties

被引：12

作者：

Roemer, Max ^{[1
]}

Schmiel, Peter ^{[1
]}

Lentz, Dieter ^{[1
]}

机构：

[1] Free Univ Berlin, Inst Chem & Biochem, D-14195 Berlin, Germany

来源：

ORGANOMETALLICS | 2011年 / 30卷 / 07期

关键词：

CRYSTAL-STRUCTURE; CYCLOPENTADIENYL COMPLEXES; ORGANOMETALLIC COMPLEXES; SUBSTITUTED FERROCENES; PENTAFLUOROPHENYL; LIGANDS; CO; METAL; FLUOROALKYLATION; PONYTAILS;

D O I：

10.1021/om2000053

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Trifluorovinylcymantrene (1) and -ferrocene (2) form the basis of a versatile building block chemistry. Di- and trinuclear complexes with perfluorinated bridging moieties are obtained by [2+2] cycloaddition on 1 and nucleophilic substitution on the C2F3 unit of 2 with cymantrenyllithium.

引用

页码：2063 / 2066

页数：4

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