Cymantrene- and Ferrocene-Based Complexes with Perfluorinated Bridging Moieties

被引：12
作者：
Roemer, Max [1 ]
Schmiel, Peter [1 ]
Lentz, Dieter [1 ]
机构：
[1] Free Univ Berlin, Inst Chem & Biochem, D-14195 Berlin, Germany
来源：
ORGANOMETALLICS | 2011年 / 30卷 / 07期
关键词：
CRYSTAL-STRUCTURE; CYCLOPENTADIENYL COMPLEXES; ORGANOMETALLIC COMPLEXES; SUBSTITUTED FERROCENES; PENTAFLUOROPHENYL; LIGANDS; CO; METAL; FLUOROALKYLATION; PONYTAILS;
D O I：
10.1021/om2000053
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Trifluorovinylcymantrene (1) and -ferrocene (2) form the basis of a versatile building block chemistry. Di- and trinuclear complexes with perfluorinated bridging moieties are obtained by [2+2] cycloaddition on 1 and nucleophilic substitution on the C2F3 unit of 2 with cymantrenyllithium.
引用
收藏
页码：2063 / 2066
页数：4
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