Novel inorganic ionic compounds based on Re6 chalcocyanide cluster complexes:: synthesis and crystal structures of [CuNH3(trien)]2[Re6S8(CN)6]•7H2O, [CuNH3(trien)]2[Re6Se8(CN)6] and [CuNH3(trien)]2[Re6Te8(CN)6]•H2O

被引：24
作者：
Brylev, KA
Naumov, NG
Peris, G
Llusar, R
Fedorov, VE
机构：
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia
[2] Univ Jaume 1, Serv Cent Instrument Cient, Castello 12071, Spain
[3] Univ Jaume 1, Dept Ciencies Expt, Castello 12071, Spain
来源：
POLYHEDRON | 2003年 / 22卷 / 25-26期
基金：
俄罗斯基础研究基金会;
关键词：
rhenium; clusters; copper; sulfur; selenium; tellurium;
D O I：
10.1016/j.poly.2003.08.015
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three new octahedral rhenium chalcocyanide cluster compounds [CuNH3(trien)](2)[Re6S8(CN)(6)].7H(2)O (1), [CuNH3(trien)](2) [Re6Se8(CN)(6)] (2) and [CuNH3(trien)](2)[Re6Te8(CN)(6)].H2O (3) exhibiting ionic structures have been obtained by the diffusion of an ammonia solution of KCs3[Re6S8(CN)(6)] (for 1), K-4[Re6Se8(CN)(6)].3.5H(2)O (for 2) or Cs-4[Re6Te8(CN)(6)].2H(2)O (for 3) into a glycerol solution of CuCl2.2H(2)O in the presence of trien (trien = triethylenetetramine). The compounds have been characterized by single-crystal X-ray diffraction. All three compounds contain a cationic complex [CuNH3(trien)](2+) which was not described previously. (C) 2003 Published by Elsevier Ltd.
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页码：3383 / 3387
页数：5
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