Asymmetric catalysis using iron complexes - 'Ruthenium Lite'?

被引:151
作者
Darwish, Muftah [1 ]
Wills, Martin [1 ]
机构
[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England
关键词
N-N-P; BIOMIMETIC TRANSFER HYDROGENATION; OLEFIN CIS-DIHYDROXYLATION; OPPENAUER-TYPE OXIDATION; DIELS-ALDER ADDITION; ENANTIOSELECTIVE EPOXIDATION; ALKENE EPOXIDATION; CARBONYL-COMPOUNDS; TRANSITION-METAL; DIOXYGEN ACTIVATION;
D O I
10.1039/c1cy00390a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A review of recent developments in the use of iron catalysts for asymmetric transformations, including hydrogenations, transfer hydrogenation, hydrosilylation and oxidation reactions.
引用
收藏
页码:243 / 255
页数:13
相关论文
共 149 条
  • [1] Chemo- and Stereoselective Iron-Catalyzed Hydrosilylation of Ketones
    Addis, Daniele
    Shaikh, Nadim
    Zhou, Shaolin
    Das, Shoubhik
    Junge, Kathrin
    Beller, Matthius
    [J]. CHEMISTRY-AN ASIAN JOURNAL, 2010, 5 (07) : 1687 - 1691
  • [2] Correlation of metal spin-state in α-diimine iron catalysts with polymerization mechanism
    Allan, Laura E. N.
    Shaver, Michael P.
    White, Andrew J. P.
    Gibson, Vernon C.
    [J]. INORGANIC CHEMISTRY, 2007, 46 (21) : 8963 - 8970
  • [3] An efficient biomimetic Fe-catalyzed epoxidation of olefins using hydrogen peroxide
    Anilkumar, Gopinathan
    Bitterlich, Bianca
    Gelalcha, Feyissa Gadissa
    Tse, Man Kin
    Beller, Matthias
    [J]. CHEMICAL COMMUNICATIONS, 2007, (03) : 289 - 291
  • [4] FeCl3-catalyzed Ritter reaction. Synthesis of amides
    Anxionnat, Bruno
    Guerinot, Amandine
    Reymond, Sebastien
    Cossy, Janine
    [J]. TETRAHEDRON LETTERS, 2009, 50 (26) : 3470 - 3473
  • [5] Arene coordination in bis(imino)pyridine iron complexes: Identification of catalyst deactivation pathways in iron-catalyzed hydrogenation and hydrosilation
    Archer, Andrew M.
    Bouwkamp, Marco W.
    Cortez, Maria-Patricia
    Lobkovsky, Emil
    Chirik, Paul J.
    [J]. ORGANOMETALLICS, 2006, 25 (18) : 4269 - 4278
  • [6] ENANTIOSELECTIVE SYNTHESES OF CYCLOPENTANOID COMPOUNDS FROM ISOPRENE AND TRANS-1,3-PENTADIENE
    BALDENIUS, KU
    DIECK, HT
    KONIG, WA
    ICHELN, D
    RUNGE, T
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1992, 31 (03): : 305 - 307
  • [7] Low-valent α-diimine iron complexes for catalytic olefin hydrogenation
    Bart, SC
    Hawrelak, EJ
    Lobkovsky, E
    Chirik, PJ
    [J]. ORGANOMETALLICS, 2005, 24 (23) : 5518 - 5527
  • [8] Preparation and molecular and electronic structures of iron(0) dinitrogen and silane complexes and their application to catalytic hydrogenation and hydrosilation
    Bart, SC
    Lobkovsky, E
    Chirik, PJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (42) : 13794 - 13807
  • [9] Well-Defined Bifunctional Iron Catalysts for the Hydrogenation of Ketones: Iron, the New Ruthenium
    Bauer, Gerald
    Kirchner, Karl A.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (26) : 5798 - 5800
  • [10] Light-Induced Enantioselective Hydrogenation Using Chiral Derivatives of Casey's Iron-Cyclopentadienone Catalyst
    Berkessel, Albrecht
    Reichau, Sebastian
    von der Hoeh, Adrian
    Leconte, Nicolas
    Neudoerfl, Joerg-M.
    [J]. ORGANOMETALLICS, 2011, 30 (14) : 3880 - 3887