Ionic liquids - An overview

被引:552
作者
Forsyth, SA [1 ]
Pringle, JM [1 ]
MacFarlane, DR [1 ]
机构
[1] Monash Univ, Sch Chem, Melbourne, Vic 3800, Australia
关键词
D O I
10.1071/CH03231
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ionic liquids have become an increasingly popular class of solvent in the last decade as the potential applications of these materials become more diverse. Rather than being viewed simply as replacement for conventional organic solvent media, research into ionic liquids has progressed to the deliberate choice and design of these materials for reasons of improved rate, specificity, and yield. Design of ionic liquids centres on the development of novel cations and anions to impart the specific physical properties required for each application. Therefore, the materials being synthesized and studied are also becoming increasingly complex and diverse. Here we provide an overview of ionic liquids generally, and some of their current applications, as well as an introduction to some of the new cations and anions that have been developed for specific properties.
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页码:113 / 119
页数:7
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共 118 条
  • [1] Conductive organic plastic crystals based on pyrazolium imides
    Abu-Lebdeh, Y
    Alarco, PJ
    Armand, M
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (37) : 4499 - 4501
  • [2] Design through the 12 principles of green engineering
    Anastas, PT
    Zimmerman, JB
    [J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2003, 37 (05) : 94A - 101A
  • [3] High-stability ionic liquids. A new class of stationary phases for gas chromatography
    Anderson, JL
    Armstrong, DW
    [J]. ANALYTICAL CHEMISTRY, 2003, 75 (18) : 4851 - 4858
  • [4] Heterogeneously catalysed selective hydrogenation reactions in ionic liquids
    Anderson, K
    Goodrich, P
    Hardacre, C
    Rooney, DW
    [J]. GREEN CHEMISTRY, 2003, 5 (04) : 448 - 453
  • [5] [Anonymous], 1992, P ELECTROCHEM SOC, DOI DOI 10.1002/jemt.22038
  • [6] Electrochemical synthesis of polyphenylene in a new ionic liquid
    Arnautov, SA
    [J]. SYNTHETIC METALS, 1997, 84 (1-3) : 295 - 296
  • [7] IONIC LIQUIDS AS SOLVENTS FOR THE REGIOSELECTIVE O-ALKYLATION OF C/O AMBIDENT NUCLEOPHILES
    BADRI, M
    BRUNET, JJ
    [J]. TETRAHEDRON LETTERS, 1992, 33 (31) : 4435 - 4438
  • [8] Synthesis of chiral ionic liquids from natural amino acids
    Bao, WL
    Wang, ZM
    Li, YX
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (02) : 591 - 593
  • [9] Hydrophobic, highly conductive ambient-temperature molten salts
    Bonhote, P
    Dias, AP
    Papageorgiou, N
    Kalyanasundaram, K
    Gratzel, M
    [J]. INORGANIC CHEMISTRY, 1996, 35 (05) : 1168 - 1178
  • [10] Industrial preparation of phosphonium ionic liquids
    Bradaric, CJ
    Downard, A
    Kennedy, C
    Robertson, AJ
    Zhou, YH
    [J]. GREEN CHEMISTRY, 2003, 5 (02) : 143 - 152