Role of Er3+ concentration in spectroscopic and laser performance of CaYAlO4 crystal

被引:19
作者
Lv, Shaozhen [1 ,2 ]
Wang, Yan [2 ]
Zhu, Zhaojie [2 ]
You, Zhenyu [2 ]
Li, Jianfu [2 ]
Wang, Hongyan [3 ]
Tu, Chaoyang [2 ]
机构
[1] Fujian Univ techonol, Fuzhou 350007, Fujian, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys CAS, Fuzhou 35002, Peoples R China
[3] Crystech Inc, Qingdao 266107, Peoples R China
基金
中国国家自然科学基金;
关键词
Mid-infrared laser; CaYAlO4; crystal; Ion concentration; MU-M EMISSION; SPECTRAL PROPERTIES; GROWTH;
D O I
10.1016/j.optmat.2015.01.012
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Three heavily Er3+-doped caYAlO(4) single crystals were successfully grown by Czochralski method. The emission spectra and the fluorescence decay curves have been recorded at room temperature. A combination of experimental data, rate equation and Dexter theory are used to investigate the influence of Er3+ doping concentration on the spectra character and the inner cross relaxation of Er3+:CaYAlO4 crystal. Results show that the self terminate effect of the transition I-4(11/2) -> I-4(13/2) can be suppressed by heavy Er(3+)doping. But if the doping concentration goes too high, the much larger cross relaxation coefficient of I-4(11/2) level than that of I-4(13/2) level would results in the increase of up-conversion emission and the quench of near and mid infrared emission. The laser performance was also studied. The maximum output power of 225 mW at 2733 nm was acquired with an optical conversion efficiency of 14.9%. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:220 / 224
页数:5
相关论文
共 18 条
[1]  
Auzel F., 1989, APPL PHYS LETT, V54, P691
[2]  
Barnes N.P., 1986, IEEE J QUANTUM ELECT, VQE-22, P237
[3]   QUANTITATIVE-ANALYSIS OF ERBIUM LUMINESCENCE IN LIYF4 DOPED WITH LOW (1.41-PERCENT) AND HIGH (38.5-PERCENT) ER+3 CONCENTRATIONS [J].
CAMARGO, MB ;
GOMES, L ;
MORATO, SP .
OPTICAL MATERIALS, 1995, 4 (05) :597-607
[4]   A THEORY OF SENSITIZED LUMINESCENCE IN SOLIDS [J].
DEXTER, DL .
JOURNAL OF CHEMICAL PHYSICS, 1953, 21 (05) :836-850
[5]   1-W AVERAGE POWER LEVELS AND TUNABILITY FROM A DIODE-PUMPED 2.94-MU-M ER-YAG OSCILLATOR [J].
HAMILTON, CE ;
BEACH, RJ ;
SUTTON, SB ;
FURU, LH ;
KRUPKE, WF .
OPTICS LETTERS, 1994, 19 (20) :1627-1629
[6]   SPECTROSCOPIC EVALUATION OF CAYALO4 DOPED WITH TRIVALENT ER, TM, YB AND HO FOR EYESAFE LASER APPLICATIONS [J].
HUTCHINSON, JA ;
VERDUN, HR ;
CHAI, BHT ;
ZANDI, B ;
MERKLE, LD .
OPTICAL MATERIALS, 1994, 3 (04) :287-306
[7]   High-order stimulated Raman scattering in tetragonal CaYAlO4 crystal-host for Ln3+-lasant ions [J].
Kaminskii, A. A. ;
Xu, X. ;
Lux, O. ;
Rhee, H. ;
Eichler, H. J. ;
Zhang, J. ;
Zhou, D. ;
Shirakawa, A. ;
Ueda, K. ;
Xu, J. .
LASER PHYSICS LETTERS, 2012, 9 (04) :306-311
[8]   Polarized spectral properties of Nd3+ ions in CaYAlO4 crystal [J].
Li, D. Z. ;
Xu, X. D. ;
Cheng, S. S. ;
Zhou, D. H. ;
Wu, F. ;
Zhao, Z. W. ;
Xia, C. T. ;
Xu, J. ;
Zhang, J. ;
Zhu, H. M. ;
Chen, X. Y. .
APPLIED PHYSICS B-LASERS AND OPTICS, 2010, 101 (1-2) :199-205
[9]   Spectroscopic investigations of Ho3+/Er3+:CaYAlO4 and Eu3+/Er3+:CaYAlO4 crystals for 2.7 μm emission [J].
Lv, Shaozhen ;
Zhu, Zhaojie ;
Wang, Yan ;
You, Zhenyu ;
Li, Jianfu ;
Tu, Chaoyang .
JOURNAL OF LUMINESCENCE, 2013, 144 :117-121
[10]  
Shi W.Q., 1990, J OPT SOC AM B, V7