Eosin Y-catalyzed one-pot synthesis of spiro[4H-pyran-oxindole] under visible light irradiation

被引：57

作者：

Chen, Meng-Nan ^{[1
]}

Di, Jia-Qi ^{[1
]}

Li, Jiao-Mian ^{[1
]}

Mo, Li-Ping ^{[1
]}

Zhang, Zhan-Hui ^{[1
]}

机构：

[1] Hebei Normal Univ, Coll Chem & Mat Sci, Natl Demonstrat Ctr Expt Chem Educ, Hebei Key Lab Organ Funct Mol, Shijiazhuang 050024, Hebei, Peoples R China

来源：

TETRAHEDRON | 2020年 / 76卷 / 14期

基金：

中国国家自然科学基金;

关键词：

Spiro [4H-pyran-oxindole; Linear 1,3-dicarbonyl compounds; Multicomponent reaction; Eosin Y; Visible light; MEDIATED RADICAL ARYLDIFLUOROACETYLATION; MULTICOMPONENT REACTIONS; 3-COMPONENT SYNTHESIS; FUNCTIONALIZED SPIROOXINDOLE; EFFICIENT SYNTHESIS; N-ARYLACRYLAMIDES; HIGHLY EFFICIENT; L-PROLINE; DERIVATIVES; METAL;

D O I：

10.1016/j.tet.2020.131059

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient and simple synthetic approach has been developed for the preparation of biologically interesting spiro[oxindole-3,4'-(4'H-pyran)] derivatives via visible light-mediated one-pot, three-component reaction of isatins, 1,3-dicarbonyl compounds and malononitrile by using an inexpensive organic dye, Na-2 eosin Y, as the photocatalyst in aqueous ethyl lactate at ambient temperature. The substrate scope of this three-component reaction is expanded to linear 1,3-dicarbonyl compounds as viable starting materials. All rights reserved. (C) 2020 Elsevier Ltd. All rights reserved.

引用

页数：11

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