Intra-chain radical chemistry as a route to poly(norbornene imide) single-chain nanoparticles: structural considerations and the role of adventitious oxygen

被引：21

作者：

Cole, Justin P. ^{[1
]}

Lessard, Jacob J. ^{[1
]}

Lyon, Christopher K. ^{[1
]}

Tuten, Bryan T. ^{[2
]}

Berda, Erik B. ^{[1
,2
]}

机构：

[1] Univ New Hampshire, Dept Chem, Durham, NH 03824 USA

[2] Univ New Hampshire, Mat Sci Program, Durham, NH 03824 USA

来源：

POLYMER CHEMISTRY | 2015年 / 6卷 / 31期

关键词：

RING-OPENING METATHESIS; POLYMER NANOPARTICLES; POLYNORBORNENE; CORE; ROMP; ATRP;

D O I：

10.1039/c5py00265f

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Attempting to design an efficient and scalable method for producing functionalized single-chain nanoparticles, we investigated intra-chain radical polymerization of pendant methacryloyl decorated poly(norbornene) imides. Upon radical initiation, nanoparticle formation ensues, but this process is relatively inefficient in these materials as currently designed. Further, we discovered that the presence of adventitious oxygen plays a key role in this system.

引用

页码：5555 / 5559

页数：5

共 33 条

[1] Single-Chain Folding of Diblock Copolymers Driven by Orthogonal H-Donor and Acceptor Units [J].

Altintas, Ozcan ;

Krolla-Sidenstein, Peter ;

Gliemann, Hartmut ;

Barner-Kowollik, Christopher .

MACROMOLECULES, 2014, 47 (17) :5877-5888

[2] A Mild and Efficient Approach to Functional Single-Chain Polymeric Nanoparticles via Photoinduced Diels-Alder Ligation [J].

Altintas, Ozcan ;

Willenbacher, Johannes ;

Wuest, Kilian N. R. ;

Oehlenschlaeger, Kim K. ;

Krolla-Sidenstein, Peter ;

Gliemann, Hartmut ;

Barner-Kowollik, Christopher .

MACROMOLECULES, 2013, 46 (20) :8092-8101

[3] Single Chain Folding of Synthetic Polymers by Covalent and Non-Covalent Interactions: Current Status and Future Perspectives [J].

Altintas, Ozcan ;

Barner-Kowollik, Christopher .

MACROMOLECULAR RAPID COMMUNICATIONS, 2012, 33 (11) :958-971

[4] Brush- First Synthesis of Core- Photodegradable Miktoarm Star Polymers via ROMP: Towards Photoresponsive Self- Assemblies [J].

Burts, Alan O. ;

Gao, Angela X. ;

Johnson, Jeremiah A. .

MACROMOLECULAR RAPID COMMUNICATIONS, 2014, 35 (02) :168-173

[5] One-pot tandem synthesis of a core - Shell brush copolymer from small molecule reactants by ring-opening metathesis and reversible addition-fragmentation chain transfer (co)polymerizations [J].

Cheng, Chong ;

Khoshdel, Ezat ;

Wooley, Karen L. .

MACROMOLECULES, 2007, 40 (07) :2289-2292

[6]

Coughlin EB, 2011, ACS SYM SER, V1066, P53

[7] Single chain polymer nanoparticles via sequential ATRP and oxidative polymerization [J].

Dirlam, Philip T. ;

Kim, Hyo Ju ;

Arrington, Kyle J. ;

Chung, Woo Jin ;

Sahoo, Rabindra ;

Hill, Lawrence J. ;

Costanzo, Philip J. ;

Theato, Patrick ;

Char, Kookheon ;

Pyun, Jeffrey .

POLYMER CHEMISTRY, 2013, 4 (13) :3765-3773

[8] Synthesis of novel cylindrical bottlebrush polypseudorotaxane via inclusion complexation of high density poly(ε-caprolactone) bottlebrush polymer and α-cyclodextrins [J].

Fu, Qiang ;

Ren, Jing M. ;

Qiao, Greg G. .

POLYMER CHEMISTRY, 2012, 3 (02) :343-351

[9] Single chain polymeric nanoparticles as compartmentalised sensors for metal ions [J].

Gillissen, Martijn A. J. ;

Voets, Ilja K. ;

Meijer, E. W. ;

Palmans, Anja R. A. .

POLYMER CHEMISTRY, 2012, 3 (11) :3166-3174

[10] Consequences of Folding a Water-Soluble Polymer Around an Organocatalyst [J].

Huerta, Elisa ;

Stals, Patrick J. M. ;

Meijer, E. W. ;

Palmans, Anja R. A. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (10) :2906-2910

← 1 2 3 4 →