Low-temperature synthesis of a green material for lithium-ion batteries cathode

被引:7
作者
Mousavi, Aliyar [1 ]
Bensalem, Azzedine [1 ]
Gee, Becky [1 ]
机构
[1] Long Isl Univ, Dept Chem & Biochem, Brooklyn, NY 11201 USA
关键词
green; rechargeable lithium batteries; lithium zinc iron phosphate; cathode; synthesis; LIFEPO4; ZINC;
D O I
10.1080/17518251003619184
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Battery technology is an important anthropogenic source of the heavy metals which are highly threatening to human health. A category of rechargeable lithium batteries that is of great interest is the set of batteries where the cathode material is a lithium iron phosphate (LiFePO(4)). LiFePO(4) is an environmentally friendly and safe lithiumion battery cathode material, but it has a key limitation, and that is its extremely low-electronic conductivity, a problem that can be greatly overcome by zinc-doping LiFePO(4). For the first time to our knowledge, a low-temperature method, that is advantageous both economically and technologically, for the synthesis of a zinc-doped LiFePO(4) is presented. Since the method appears to be applicable for synthesizing various zinc-doped LiFePO(4) compounds with the general formula LiFe(1-x)Zn(x)PO(4) (0 < x < 1), it is very promising for the production of a green cathode material for lithium-ion batteries.
引用
收藏
页码:135 / 142
页数:8
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