Synthesis of a paramagnetic polymer by ring-opening polymerization of a strained [1]vanadoarenophane

被引：31

作者：

Braunschweig, Holger ^{[1
]}

Adams, Christopher J. ^{[2
]}

Kupfer, Thomas ^{[1
]}

Manners, Ian ^{[2
]}

Richardson, Robert M. ^{[3
]}

Whittell, George R. ^{[2
]}

机构：

[1] Julius Maximilians Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

[2] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

[3] Univ Bristol, HH Wills Phys Lab, Bristol BS8 1TL, Avon, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 20期

关键词：

ansa complexes; EPR spectroscopy; organometallic polymers; ring-opening polymerization; vanadium;

D O I：

10.1002/anie.200800081

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Salt-elimination reactions led to the formation of highly strained [1]bora- and [1]silavanadoarenophanes, which undergo different types of ring-opening reactions with low-valent platinum complexes. Whereas the boron-bridged derivative opened stoichiometrically by cleavage of the V-Carene bond, the [1]silavanadoarenophane reacted at the Si-Cipso bond to afford a polymer containing spinactive metalcenters in the main chain (see scheme). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3826 / 3829

页数：4

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