New mixed tellurides of nickel and Group 13-14 metals Ni3-δMTe2 (M=Sn, In, Ga)

被引：11
|
作者：
Litvinenko, O. N. [1 ]
Kuznetsov, A. N. [2 ]
Olenev, A. V. [2 ]
Popovkin, B. A. [2 ]
机构：
[1] Moscow MV Lomonosov State Univ, Dept Mat Sci, Moscow 119992, Russia
[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2007年 / 56卷 / 10期
基金：
俄罗斯基础研究基金会;
关键词：
low-dimensional phases; layered phases; nickel-main group metal bonds; nickel subvalent tellurides;
D O I：
10.1007/s11172-007-0301-z
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Three new mixed tellurides of nickel and group 13-14 metals Ni3-delta MTe2 (M = Sn, In, Ga) were prepared by high-temperature ampoule synthesis and studied by powder X-ray diffraction analysis. The compound Ni3-delta SnTe2 was also studied by single crystal X-ray diffraction analysis. The structural model of this phase and two analogs was described as consisting of layers with nickel-main group metal bonds confined from the above by tellurium atoms. The van der Waals gap formed through contacts between the tellurium atoms of neighboring layers is partially occupied by nickel atoms.
引用
收藏
页码：1945 / 1947
页数：3
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