Importance of Micropore-Mesopore Interfaces in Carbon Dioxide Capture by Carbon-Based Materials

被引：70
|
作者：
Dura, Gema [1 ]
Budarin, Vitaliy L. [1 ]
Castro-Osma, Jose A. [2 ]
Shuttleworth, Peter S. [3 ]
Quek, Sophie C. Z. [1 ]
Clark, James H. [1 ]
North, Michael [1 ]
机构：
[1] Univ York, Dept Chem, Green Chem Ctr Excellence, York YO10 5DD, N Yorkshire, England
[2] Univ Castilla La Mancha, Dept Quim Inorgan Organ & Bioquim, Ctr Innovac Quim Avanzada ORFEO CINQA, IRICA, E-13071 Ciudad Real, Spain
[3] CSIC, Inst Ciencia & Tecnol Polimeros, Dept Fis Polimeros Elastomeros & Aplicac Energet, C Juan Cierva 3, Madrid 28006, Spain
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2016年 / 55卷 / 32期
关键词：
adsorption; carbon dioxide capture; carbon materials; mesoporous materials; separation; HIGH-PRESSURE ADSORPTION; CO2; ADSORPTION; MOLECULAR-SIEVES; POROUS MATERIALS; ZEOLITE; SEPARATION;
D O I：
10.1002/anie.201602226
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Mesoporous carbonaceous materials (Starbons (R)) derived from low-value/waste bio-resources separate CO2 from CO2/N-2 mixtures. Compared to Norit activated charcoal (AC), Starbons (R) have much lower microporosities (8-32% versus 73%) yet adsorb up to 65% more CO2. The presence of interconnected micropores and mesopores is responsible for the enhanced CO2 adsorption. The Starbons (R) also showed three-four times higher selectivity for CO2 adsorption rather than N-2 adsorption compared to AC.
引用
收藏
页码：9173 / 9177
页数：5
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