Highly dispersed carbon-supported Pd nanoparticles catalyst synthesized by novel precipitation-reduction method for formic acid electrooxidation

被引：31

作者：

Liang, Yan ^{[1
]}

Zhu, Mengna ^{[1
]}

Ma, Juan ^{[2
]}

Tang, Yawen ^{[1
]}

Chen, Yu ^{[1
]}

Lu, Tianhong ^{[1
]}

机构：

[1] Nanjing Normal Univ, Jiangsu Key Lab New Power Batteries, Lab Electrochem, Coll Chem & Mat Sci, Nanjing 210046, Peoples R China

[2] Soochow Univ, Inst Chem Power Sources, Suzhou 215006, Peoples R China

来源：

ELECTROCHIMICA ACTA | 2011年 / 56卷 / 12期

基金：

中国国家自然科学基金;

关键词：

Catalyst; Precipitation-reduction method; Formic acid; Electrooxidation; Electrocatalytic activity; SELF-ASSEMBLED MONOLAYERS; OXYGEN REDUCTION; PARTICLE-SIZE; ELECTROCATALYTIC OXIDATION; PALLADIUM NANOPARTICLES; ANODIC CATALYST; HYDRODECHLORINATION; PERFORMANCE; ALLOY; NANOCATALYSTS;

D O I：

10.1016/j.electacta.2011.03.019

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The highly dispersed and ultrafine carbon-supported Pd nanoparticles (Pd/C) catalyst is synthesized by using an improved precipitation-reduction method, which involves in Pd-II -> PdO center dot H2O Pd-0 reaction path. In the method, palladium oxide hydrate (PdO center dot H2O) nanoparticles (NPs) with high dispersion is obtained easily by adjusting solution pH in the presence of 1,4-butylenediphosphonic acid (H2O3P-(CH2)(4)-PO3H2, BDPA). After NaBH4 reduction, the resulting Pd/C catalyst possesses high dispersion and small particle size. As a result, the electrochemical measurements indicate that the resulting Pd/C catalyst exhibits significantly high electrochemical active surface area and high electrocatalytic performance for formic acid electrooxidation compared with that prepared by general NaBN4 reduction method. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：4696 / 4702

页数：7

共 67 条

[61] Highly Active Carbon-supported PdSn Catalysts for Formic Acid Electrooxidation [J].