On the Role of CO2 in NHC-Catalyzed Oxidation of Aldehydes

被引：97

作者：

Chiang, Pei-Chen

Bode, Jeffrey W. ^{[1
]}

机构：

[1] Univ Penn, Dept Chem, Philadelphia, PA 19104 USA

来源：

ORGANIC LETTERS | 2011年 / 13卷 / 09期

关键词：

N-HETEROCYCLIC CARBENE; ENVIRONMENTALLY BENIGN OXIDATION; CARBON-DIOXIDE; AROMATIC-ALDEHYDES; BOND-CLEAVAGE; CONVERSION; DECARBOXYLATION; ORGANOCATALYSTS; CARBOXYLATES; MECHANISM;

D O I：

10.1021/ol2006538

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

NHC-catalyzed oxidations using carbon dioxide as the stoichiometric oxidant have been carefully investigated. These studies support a secondary role of CO2 in suppressing side reactions and exogenous oxygen as the actual oxidant.

引用

页码：2422 / 2425

页数：4

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