Role of copper on structural, magnetic and dielectric properties of nickel ferrite nano particles

被引:27
作者
Balavijayalakshmi, J. [1 ]
Suriyanarayanan, N. [2 ]
Jayaprakash, R. [3 ]
机构
[1] PSGR Krishnammal Coll Women, Dept Phys, Coimbatore 641004, Tamil Nadu, India
[2] Govt Coll Technol, Dept Phys, Coimbatore, Tamil Nadu, India
[3] Sri Ramakrishna Mission Vidyalaya Coll Arts & Sci, Dept Phys, Nanotechnol Lab, Coimbatore, Tamil Nadu, India
关键词
Co-precipitation; Nanoparticles; FT-IR; Coercivity; Vibrating Sample Magnetometer; Sintering; CITRATE PRECURSOR METHOD; GEL AUTO-COMBUSTION; ZN FERRITES; ZN1-XNIXFE2O4;
D O I
10.1016/j.jmmm.2015.03.036
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Copper doped nickel ferrites Ni(1-x)CuxFe2O4 (where x=0.2, 0.4, 0.6) nanoparticles are prepared by coprecipitation method and sintered at 600 degrees C. The XRD study confirms the formation of single-phase cubic spinet Ni-Cu ferrites. The particle size increases with Cu substitution. FT-IR spectra confirm the absorption bands around 554-547 cm(-1) for the tetrahedral sites and around 448-450 cm(-1) for the octahedral sites. The inclusion of copper shifts the tetrahedral band to lower values. The saturation magnetization (M-s) and remanent magnetization (M-r) decrease with increase in copper concentration and the coercivity (H-c) is found to increase for all the compositions sintered at 600 degrees C. The dielectric constant decreases drastically for all the compositions and reaches a constant value. These nanoparticles can be tested for humidity sensing applications. (C) 2015 Elsevier B.V. All rights reserved
引用
收藏
页码:302 / 307
页数:6
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