2,5-Furandicarboxylic Acid: An Intriguing Precursor for Monomer and Polymer Synthesis

被引：37

作者：

Marshall, Adam ^{[1
]}

Jiang, Bo ^{[1
]}

Gauvin, Regis M. ^{[1
]}

Thomas, Christophe M. ^{[1
]}

机构：

[1] PSL Univ, Chim ParisTech, CNRS, Inst Rech Chim Paris, F-75005 Paris, France

来源：

MOLECULES | 2022年 / 27卷 / 13期

关键词：

biobased monomers; sustainable polymers; furan-based materials; DECOMPOSITION MECHANISM; BIOMASS; POLYESTERS; CONVERSION; HUMINS; ETHERIFICATION; CARBOXYLATION; VALORIZATION; DEGRADATION; COMPONENTS;

D O I：

10.3390/molecules27134071

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The most versatile furanic building block for chemical and polymer applications is 2,5-furandicarboxylic acid. However, the classical 2,5-furandicarboxylic acid production methodology has been found to have significant drawbacks that hinder industrial-scale production. This review highlights new alternative methods to synthesize 2,5-furandicarboxylic acid that are both more advantageous and attractive than conventional oxidation of 5-hydroxymethylfurfural. This review also focuses on the use of 2,5-furandicarboxylic acid as a polymer precursor and the various potential applications that arise from these furan-based materials.

引用

页数：24

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