2,5-Furandicarboxylic Acid: An Intriguing Precursor for Monomer and Polymer Synthesis

被引:37
作者
Marshall, Adam [1 ]
Jiang, Bo [1 ]
Gauvin, Regis M. [1 ]
Thomas, Christophe M. [1 ]
机构
[1] PSL Univ, Chim ParisTech, CNRS, Inst Rech Chim Paris, F-75005 Paris, France
关键词
biobased monomers; sustainable polymers; furan-based materials; DECOMPOSITION MECHANISM; BIOMASS; POLYESTERS; CONVERSION; HUMINS; ETHERIFICATION; CARBOXYLATION; VALORIZATION; DEGRADATION; COMPONENTS;
D O I
10.3390/molecules27134071
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The most versatile furanic building block for chemical and polymer applications is 2,5-furandicarboxylic acid. However, the classical 2,5-furandicarboxylic acid production methodology has been found to have significant drawbacks that hinder industrial-scale production. This review highlights new alternative methods to synthesize 2,5-furandicarboxylic acid that are both more advantageous and attractive than conventional oxidation of 5-hydroxymethylfurfural. This review also focuses on the use of 2,5-furandicarboxylic acid as a polymer precursor and the various potential applications that arise from these furan-based materials.
引用
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页数:24
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