Dry polymer electrolytes are a promising class of materials for future safer high-energy-density battery technologies. This review deals with the relevant physico-chemical properties of the dry polymer electrolytes, ionic transport mechanism, molecular structure, and interfacial issues in a widely investigated model system (poly(ethylene oxide) with lithium bis(trifluoromethanesulfonyl)imide). At the end of the review, latest macromolecular approaches for high-performance lithium battery applications are discussed.
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