Synthesis, crystal structures, and properties of three metal complexes with N-phenylanthranilic acid

被引：20
|
作者：
Tan, Yu-Hui [1 ]
Xiong, Jian-Bo [1 ]
Gao, Ji-Xing [1 ]
Xu, Qing [1 ]
Fu, Chao-Wu [1 ]
Tang, Yun-Zhi [1 ]
Yang, Shao-Ping [2 ]
Wen, He-Rui [1 ]
机构：
[1] Jiangxi Univ Sci & Technol, Sch Met & Chem Engn, Ganzhou 341000, Peoples R China
[2] Wuzhou Univ, Sch Chem Engn & Resource Reuse, Wuzhou 543002, Peoples R China
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2015年 / 1086卷
基金：
中国国家自然科学基金;
关键词：
Hydrothermal reactions; N-donor ligands; Crystal structures; Fluorescence properties; COORDINATION POLYMERS; ORGANIC FRAMEWORKS; PHOTOLUMINESCENT PROPERTIES; LIGANDS; ZINC; CARBOXYLATE; ASSEMBLIES; CD(II); DNA;
D O I：
10.1016/j.molstruc.2015.01.005
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The hydrothermal reactions between N-phenylanthranilic acid (NPA), transition metal hydroxide salts and ex-bidentate N-donor ligands in CH3CH2OH/H2O solutions afforded three new complexes, [Cd-1.5(NPA)(3)(2,2'-bipy)] (1), [Zn(NPA)(2)(2,2'-bipy)] (2,2'-bipy = 2,2'-bipyridine) (2) and [Mn(NPA)(2)(Phen)(2)] (Phen = 1,10-phenanthroline) (3). X-ray structural determination indicates that all of the title complexes crystallize in the same triclinic crystal system with space group p (1) over bar. Complex 1 displays a symmetrical trinuclear aggregate, while complexs 2 and 3 display mononuclear structures. All the NPA ligands adopt total different coordination modes in complexes 1, 2 and 3. The comparison of solid-state fluorescence spectra among 1, 2 and free NPA shows that 1 and 2 exist a large red-shifted emission compared to free NPA ligand. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：49 / 55
页数：7
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