The solvothermal synthesis of a 3D rod-like Fe-Al bimetallic metal-organic-framework for efficient fluoride adsorption and photodegradation of water-soluble carcinogenic dyes

A thermally stable, 3D rod-like, nanosized, porous, pH-stable Fe-Al bimetallic metal-organic-framework with terephthalic acid (1,4-benzenedicarboxylic acid) as a linker (abbreviated to Fe-Al BDC) with a surface area of 120.255 m2 g-1 was synthesized using a solvothermal method for fluoride adsorption and the photodegradation of rhodamine B (RhB)/methylene blue (MB) within a pH range of 2-11. The mu-oxo metal bonds and 3D rod-like structure of Fe-Al BDC were determined via PXRD, FTIR, Raman spectroscopy, and FESEM analyses. The relationship between the particle size and surface area obeyed the Andre relationship. The chemisorption of fluoride, supported by XPS and FTIR studies, obeyed pseudo-second-order kinetics, with a Langmuir/Freundlich adsorption isotherm, and thermodynamic studies were undertaken. RhB/MB (10-5/10-4 M) photodegraded under solar irradiation following pseudo-first-order kinetics. The surface-boundary-layer fluoride adsorption mechanism is confirmed based on the interparticle-diffusion model and mass-transfer model supported by xi-potential analysis, and the mineralization mechanism of RhB was established using Kroger-Vink notation and HPLC studies; the material was reusable for up to eight cycles. Thermally stable, 3D rod-like, nanosized, pH-stable Fe-Al metal-organic-framework with terephthalic acid as a linker with a surface area 120.255 m2 g-1 was synthesized solvothermally for fluoride adsorption and the photodegradation of rhodamine B/methylene blue (pH 2-11).