On the nature of the transition metal-main group metal bond: synthesis and theoretical calculations on iridium gallyl complexes

被引：23

作者：

Durango-Garcia, Clara J. ^{[1
]}

Jimenez-Halla, J. Oscar C. ^{[2
]}

Lopez-Cardoso, Marcela ^{[1
]}

Montiel-Palma, Virginia ^{[1
]}

Munoz-Hernandez, Miguel A. ^{[1
]}

Merino, Gabriel ^{[2
]}

机构：

[1] Univ Autonoma Estado Morelos, Ctr Invest Quim, Cuernavaca, Morelos, Mexico

[2] Univ Guanajuato, Dept Quim, Div Ciencias Nat & Exactas, Guanajuato 36050, Mexico

来源：

DALTON TRANSACTIONS | 2010年 / 39卷 / 44期

关键词：

INDIUM; GA; REACTIVITY; CHEMISTRY; AL; TL;

D O I：

10.1039/c0dt01071e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The iridum-gallyl complex MeIr(PCy3)(2)(GaMe2)((ClGaMe3)-Ga-center dot) exhibits a short Ir-Ga bond length of 2.381(1)-2.389(2) angstrom. Theoretical calculations (ZORA BP86/TZ2P) support the presence of a Ir-Ga single bond but highlight a pi orbital contribution.

引用

页码：10588 / 10589

页数：2

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