Direct conversion of syngas to aromatics

被引：195
作者：
Yang, Junhao [1 ,2 ]
Pan, Xiulian [1 ]
Jiao, Feng [1 ,2 ]
Li, Jian [1 ,2 ]
Bao, Xinhe [1 ]
机构：
[1] Chinese Acad Sci, Dalian Inst Chem Phys, Collaborat Innovat Ctr Chem Energy Mat 2011, State Key Lab Catalysis,Natl Lab Clean Energy, Zhongshan Rd 457, Dalian 116023, Peoples R China
[2] Univ Chinese Acad Sci, Yuquan Rd 19A, Beijing 100049, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 81期
关键词：
METHANE DEHYDROAROMATIZATION; LOWER OLEFINS; BIFUNCTIONAL CATALYSIS; SELECTIVE CONVERSION; MO/ZSM-5; CATALYSTS; ZEOLITE CATALYSTS; LIGHT OLEFINS; AROMATIZATION; 1,2,4-TRIMETHYLBENZENE; MO/HZSM-5;
D O I：
10.1039/c7cc04768a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A composite catalyst combining the partially reducible ZnCrOx with zeolite ZSM-5 enables direct conversion of syngas to aromatics, with a selectivity to aromatics reaching 73.9% at a single pass CO conversion of 16.0%.
引用
收藏
页码：11146 / 11149
页数：4
相关论文
共 28 条
[1]   Composition and quality of the gasoline obtained from syngas on Cr2O3-ZnO/ZSM5 catalysts [J].
Arandes, JM ;
Ereña, J ;
Gayubo, AG ;
Bilbao, J ;
De Lasa, HI .
CHEMICAL ENGINEERING COMMUNICATIONS, 1999, 174 :1-19
[2]  
Chang C. D., 1974, CHANG CD
[3]   CONVERSION OF ALCOHOLS TO AROMATICS ON H-ZSM-5 - INFLUENCE OF SI/AL RATIO AND DEGREE OF CATION-EXCHANGE ON PRODUCT DISTRIBUTION [J].
CHOUDHARY, VR ;
NAYAK, VS .
ZEOLITES, 1985, 5 (05) :325-328
[4]   Catalysts for Production of Lower Olefins from Synthesis Gas: A Review [J].
Galvis, Hirsa M. Torres ;
de Jong, Krijn P. .
ACS CATALYSIS, 2013, 3 (09) :2130-2149
[5]   Supported Iron Nanoparticles as Catalysts for Sustainable Production of Lower Olefins [J].
Galvis, Hirsa M. Torres ;
Bitter, Johannes H. ;
Khare, Chaitanya B. ;
Ruitenbeek, Matthijs ;
Dugulan, A. Iulian ;
de Jong, Krijn P. .
SCIENCE, 2012, 335 (6070) :835-838
[6]   Direct conversion of methane on Mo/ZSM-5 catalysts to produce benzene and hydrogen: achievements and perspectives [J].
Ismagilov, Zinfer R. ;
Matus, Ekaterina V. ;
Tsikoza, Lidia T. .
ENERGY & ENVIRONMENTAL SCIENCE, 2008, 1 (05) :526-541
[7]   Selective conversion of syngas to light olefins [J].
Jiao, Feng ;
Li, Jinjing ;
Pan, Xiulian ;
Xiao, Jianping ;
Li, Haobo ;
Ma, Hao ;
Wei, Mingming ;
Pan, Yang ;
Zhou, Zhongyue ;
Li, Mingrun ;
Miao, Shu ;
Li, Jian ;
Zhu, Yifeng ;
Xiao, Dong ;
He, Ting ;
Yang, Junhao ;
Qi, Fei ;
Fu, Qiang ;
Bao, Xinhe .
SCIENCE, 2016, 351 (6277) :1065-1068
[8]   Bifunctional catalysis of Mo/HZSM-5 in the dehydroaromatization of methane with CO/CO2 to benzene and naphthalene [J].
Liu, S ;
Wang, L ;
Ohnishi, R ;
Ichikawa, M .
KINETICS AND CATALYSIS, 2000, 41 (01) :132-144
[9]   Bifunctional catalysis of Mo/HZSM-5 in the dehydroaromatization of methane to benzene and naphthalene XAFS/TG/DTA/MASS/FTIR characterization and supporting effects [J].
Liu, ST ;
Wang, L ;
Ohnishi, R ;
Ichikawa, M .
JOURNAL OF CATALYSIS, 1999, 181 (02) :175-188
[10]   A high coking-resistance catalyst for methane aromatization [J].
Lu, Y ;
Ma, D ;
Xu, ZS ;
Tian, ZJ ;
Bao, XH ;
Lin, LW .
CHEMICAL COMMUNICATIONS, 2001, (20) :2048-2049
123