Impact of Negative Line Tension on the Shape of Nanometer-Size Sessile Droplets

被引:76
作者
Berg, John K. [1 ]
Weber, Constans M. [1 ]
Riegler, Hans [1 ]
机构
[1] Max Planck Inst Colloids & Interfaces, D-14424 Potsdam, Germany
关键词
ATOMIC-FORCE MICROSCOPY; WETTING TRANSITIONS; CONTACT ANGLES; SURFACES; INTERFACE; DOMAINS; FLUID; MODEL; MONOLAYERS; MEMBRANES;
D O I
10.1103/PhysRevLett.105.076103
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The sign and value of the line tension has been measured from the size dependence of the contact angle of nanometer-size sessile fullerene (C(60)) droplets on the planar SiO(2) interface, measured with atomic force microscopy (AFM). Analysis according to the modified Young's equation indicates a negative line tension, with a magnitude between -10(-11) and -10(-10) N/m, in good agreement with theoretical predictions. The experiments also indicate that droplets with contact area radii below 10 nm are in fact two-dimensional round terraces.
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页数:4
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