Isolation and structure of a europium(III) chloride complex of 2,6-bis[(diphenylphosphino)methyl]pyridine N,P,P′-trioxide

被引：26
作者：
Bond, EM
Duesler, EN
Paine, RT [1 ]
Nöth, H
机构：
[1] Univ New Mexico, Dept Chem, Albuquerque, NM 87131 USA
[2] Univ Munich, Dept Chem, D-81377 Munich, Germany
来源：
POLYHEDRON | 2000年 / 19卷 / 20-21期
关键词：
lanthanide complex; tridentate chelate; europium(III) chloride;
D O I：
10.1016/S0277-5387(00)00519-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The combination of EuCl3. 6H(2)O with the trifunctional ligand 2,6-[(C6H5)(2)P(O)CH2](2)C5H3NO. in a 1:2 ratio, produces the coordination complex [Eu{[(C6H5)(2)P(O)CH2](2)C5H3NO} (2)(H2O)(2)]Cl-3. 9H(2)O. The molecular structure of the complex has been determined by single-crystal X-ray diffraction methods. The. N,P,P'-trioxide ligands each bind to the central Eu(III) ion in a tridentate fashion along with two water molecules. The eight inner sphere oxygen atoms surrounding the Eu(III) ion form a square antiprism. These results are discussed in the context of the structures formed by lanthanide nitrates. (C) 2000 Elsevier Science B.V. All rights reserved.
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页码：2135 / 2140
页数：6
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