catena-Poly[[ diaquacadmium(II)]-μ-4-(carboxylatomethylsulfanyl)phenoxyacetato]

被引：4

作者：

Gao, S

Su, H

Huo, LH

Ng, SW ^{[1
]}

机构：

[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia

[2] Heilongjiang Univ, Coll Chem & Chem Technol, Harbin 150080, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2005年 / 61卷

关键词：

D O I：

10.1107/S1600536805008500

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The dicarboxylate dianion in the polymeric title compound, [Cd(C10H8O3S)(H2O)(2)](n), links diaquacadmium(II) units into a zigzag chain. Adjacent chains are linked by hydrogen bonds into a layered structure. The coordination geometry of the Cd atom is octahedral, with Cd - O-COO distances of 2.395 (3) and 2.359 ( 3) angstrom, and a Cd - O-aqua distance of 2.193 ( 4) angstrom. The Cd atom lies on a twofold rotation axis.

引用

页码：M725 / M726

页数：2

共 8 条

[1] Diaqua(benzene-1,4-dioxyacetate)zinc(II): a one-dimensional zigzag chain [J].

Gao, S ;

Liu, JW ;

Huo, LH ;

Zhao, H ;

Ng, SW .

APPLIED ORGANOMETALLIC CHEMISTRY, 2005, 19 (01) :169-170

[2] Poly[zinc(II)-μ4-1,4-phenylenedioxydiacetato-κ2O:O′] [J].

Gao, S ;

Liu, JW ;

Huo, LH ;

Zhao, H ;

Ng, SW .

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 :M1370-M1371

[3]

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[4]

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[5]

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[6]

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[7]

Sheldrick G. M., 1997, SHELXS 97 PROGRAM CR

[8]

Sheldrick G M, 1997, SHELXS 97 PROGRAM CR

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