Four-electron electrocatalytic reduction of dioxygen to water by an ion-pair cobalt porphyrin dimer adsorbed on a glassy carbon electrode

被引：45

作者：

D'Souza, F ^{[1
]}

Hsieh, YY ^{[1
]}

Deviprasad, GR ^{[1
]}

机构：

[1] Wichita State Univ, Dept Chem, Wichita, KS 66720 USA

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 09期

关键词：

D O I：

10.1039/a708768c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An ion-pair porphyrin dimer, formed by reacting the tetrachloro salt of [tetrakis(N-methylpyridyl)porphyrinato]cobalt and the tetrasodium salt of [tetrakis(4-sulfonatophenyl)porphyrinato]cobalt, adsorbed electrochemically on a glassy carbon electrode is shown to catalytically reduce O-2 to water by four electrons.

引用

页码：1027 / 1028

页数：2

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