Densities at pressures up to 20 MPa and thermal conductivities at 0.1 MPa of 1-butyl-3-methylimidazolium tetrafluoroborate plus methanol mixtures

被引:0
作者
Tomida, Daisuke [1 ]
Odashima, Tsuyoshi [1 ]
Qiao, Kun [1 ]
Yokoyama, Chiaki [1 ]
机构
[1] Tohoku Univ, Inst Multidisciplinary Res Adv Mat, Aoba Ku, 2-1-1 Katahira, Sendai, Miyagi 9808577, Japan
关键词
1-Butyl-3-methylimidazolium tetrafluoroborate; Density; Ionic liquid; Methanol; Thermal conductivity; Transient short hot-wire; High Pressure; TEMPERATURE IONIC LIQUIDS; VOLUMETRIC PROPERTIES; REFRACTIVE-INDEXES; DIMETHYL CARBONATE; ORGANIC-SOLVENTS; BINARY-MIXTURES; MOLAR VOLUMES; VISCOSITY; EXCESS; WATER;
D O I
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中图分类号
O414.1 [热力学];
学科分类号
摘要
In this study, we report densities and thermal conductivities for 1-butyl-3-methylimidazolium tetrafluoroborate + methanol mixtures. The densities were measured using a vibrating tube densimeter over the temperature range 293-333 K and at pressures up to 20 MPa. The expanded uncertainty in the density measurements was 0.22% (k = 2). The experimental values were correlated with a Tait equation with an average absolute deviation of 0.10%. The transient short hot-wire method was used to measure the thermal conductivities over the temperature range 295-335 K at 0.1 MPa. The expanded uncertainty in the thermal conductivity measurements was 4.4%. The thermal conductivities of the 1-butyl-3-methylimidazolium tetrafluoroborate + methanol mixtures increased in an approximately quadratically with increasing methanol mass fraction. The experimental values were correlated with a Jamieson equation with an average absolute deviation of 0.24%.
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页码:299 / 310
页数:12
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