Preparation of polystyrene-supported Lewis acidic Fe(III) ionic liquid and its application in catalytic conversion of carbon dioxide

被引：73
作者：
Gao, Jian
Song, Qing-Wen
He, Liang-Nian [1 ]
Liu, Chang
Yang, Zhen-Zhen
Han, Xu
Li, Xue-Dong
Song, Qing-Chuan
机构：
[1] Nankai Univ, State Key Lab, Tianjin 300071, Peoples R China
来源：
TETRAHEDRON | 2012年 / 68卷 / 20期
基金：
中国国家自然科学基金;
关键词：
Carbon dioxide; Iron-containing ionic liquid; Cycloaddition; Heterogeneous catalyst; Cyclic carbonates; CO2 CYCLOADDITION REACTIONS; QUATERNARY AMMONIUM-SALT; N-HETEROCYCLIC CARBENES; CYCLIC CARBONATES; CHEMICAL FIXATION; SUPERCRITICAL CONDITIONS; PROPYLENE CARBONATE; COUPLING REACTIONS; HIGHLY EFFICIENT; HETEROGENEOUS CATALYST;
D O I：
10.1016/j.tet.2012.03.048
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A polystyrene-supported Lewis acidic iron-containing ionic liquid was proved to be recyclable and efficient heterogeneous catalyst for converting CO2 into cyclic carbonate without utilization of any organic solvent or additive. Excellent yields and selectivity were obtained under mild reaction conditions. Notably, the catalyst could be readily recovered and reused over five times without appreciable loss of catalytic activity. A possible catalytic cycle was proposed. The present protocol has successfully been applied to reactions of aziridines/propargyl amines with CO2. This kind of the catalyst presented herein would have great potential in industrial application thanks to its featured advantages. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码：3835 / 3842
页数：8
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