Synthesis and characterization of nanocomposite of polyvinyl alcohol and lead sulfide nanoparticles

被引：93

作者：

Kuljanin, J ^{[1
]}

Comor, MI ^{[1
]}

Djokovic, V ^{[1
]}

Nedeljkovic, JM ^{[1
]}

机构：

[1] Vinca Inst Nucl Sci, Belgrade 11001, Serbia Monteneg

来源：

MATERIALS CHEMISTRY AND PHYSICS | 2006年 / 95卷 / 01期

关键词：

nanocomposite; colloidal chemistry method; thermal decomposition; mechanical properties;

D O I：

10.1016/j.matchemphys.2005.05.050

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The nanocomposites consisting of lead sulfide (PbS) nanoparticles (NPs) with average diameter of 26 angstrom and polyvinyl alcohol (PVA) were synthesized using colloidal chemistry methods. The PbS/PVA nanocomposites were characterized using optical, structural, thermal and mechanical techniques. No difference between infrared spectra and no difference between glass transition temperatures after incorporation of the PbS NPs in the PVA matrix indicated weak interaction between nanofilter and polymer. Due to weak interaction between nanofilter and polymer a slight improvement of the mechanical Properties of the PbS/PVA nanocomposite was observed compared to the neat PVA. On the other hand, the presence of the PbS NPs in the PVA matrix induced the increase of the crystallization temperature and enthalpy of crystallization. Also, the thermal decomposition of the PVA shifted towards higher temperature for about 15 degrees C in the presence of the PbS NPs. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：67 / 71

页数：5

共 31 条

[11] ENCAPSULATION OF LEAD SULFIDE MOLECULAR CLUSTERS INTO SOLID MATRICES - STRUCTURAL-ANALYSIS WITH X-RAY ABSORPTION-SPECTROSCOPY [J].