A polyoxometalate-based single-molecule magnet with an S=21/2 ground state

被引：85

作者：

Fang, Xikui ^{[1
,2
]}

Koegerler, Paul ^{[3
]}

Speldrich, Manfred ^{[3
]}

Schilder, Helmut ^{[3
]}

Luban, Marshall ^{[1
,2
]}

机构：

[1] Iowa State Univ, US DOE, Ames Lab, Ames, IA 50011 USA

[2] Iowa State Univ, Dept Phys & Astron, Ames, IA 50011 USA

[3] Rhein Westfal TH Aachen, Inst Inorgan Chem, D-52074 Aachen, Germany

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 09期

关键词：

MANGANESE CARBOXYLATE; BISTABILITY; COMPLEXES; CLUSTER; ION;

D O I：

10.1039/c1cc15520b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ligand modification transforms a polyoxometalate-anchored cubane-type [Mn(3)(III)Mn(IV)O(4)] core into a centrosymmetric [Mn(6)(III)Mn(IV)O(8)] di-cubane cluster, and restores the slow magnetization relaxation characteristics typical for [Mn(4)O(4)] cubane-based single-molecule magnets.

引用

页码：1218 / 1220

页数：3

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