Direct observation of denitrogenation process of 2,3-diazabicyclo[2.2.1]hept-2-ene (DBH) derivatives, using a visible 5-fs pulse laser

被引：9

作者：

Abe, Manabu ^{[1
,2
]}

Iwakura, Izumi ^{[1
,3
]}

Yabushita, Atushi ^{[4
]}

Yagi, Shingo ^{[1
]}

Liu, Jun ^{[2
,5
]}

Okamura, Kotaro ^{[5
]}

Kobayashi, Takayoshi ^{[2
,4
,5
,6
]}

机构：

[1] Hiroshima Univ, Grad Sch Sci, Dept Chem, Hiroshima 7398526, Japan

[2] JST, CREST, Chiyoda Ku, Tokyo 1020076, Japan

[3] JST, PRESTO, Kawaguchi, Saitama 3320012, Japan

[4] Natl Chiao Tung Univ, Dept Electrophys, Hsinchu 300, Taiwan

[5] Univ Electrocommun, Adv Ultrafast Laser Res Ctr, Chofu, Tokyo 1828585, Japan

[6] Osaka Univ, Inst Laser Engn, Suita, Osaka 5650971, Japan

来源：

CHEMICAL PHYSICS LETTERS | 2012年 / 527卷

关键词：

REAL-TIME SPECTROSCOPY; THERMAL DENITROGENATION; PHOTOCHEMICAL DENITROGENATION; TRANSITION-STATES; ZUR STEREOCHEMIE; DOUBLE-INVERSION; AZOALKANES; MECHANISM; DEAZETIZATION; REARRANGEMENT;

D O I：

10.1016/j.cplett.2012.01.024

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The mechanism of denitrogenation for 2,3-diazabicyclo[2.2.1]hept-2-ene (DBH) derivatives was investigated using a visible 5-fs pulse laser. The time-dependent wavenumber changes observed in this study revealed that the concerted denitrogenation occurs in the parent DBH. However, a stepwise denitrogenation mechanism was found for the 7,7-diethoxy-substituted DBH derivative. (C) 2012 Elsevier B. V. All rights reserved.

引用

页码：79 / 83

页数：5

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