2-(Imidazol-1-yl)-4-methylphenol

被引:7
|
作者
Naruta, Y [1 ]
Tachi, Y [1 ]
Chishiro, T [1 ]
Shimazaki, Y [1 ]
Tani, F [1 ]
机构
[1] Kyushu Univ, Inst Fundamental Res Organ Chem, Higashi Ku, Fukuoka 8128581, Japan
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2001年 / 57卷
关键词
D O I
10.1107/S1600536801008492
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, C10H10N2O, was synthesized to investigate the structure of the Tyr-His residue in the active site of cytochrome c oxidase (CcO). The dihedral angle between the cresol and imidazole moieties is 42.21 (4)degrees, which is similar to that of the tyrosine-linked histidine in bovine heart CcO. In the title compound, the R and S enantiomers of axial chirality are connected by an O-H . . .N hydrogen bond.
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页码:o550 / o552
页数:3
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