Component exchange as a synthetically advantageous strategy for the preparation of bicyclic cage compounds

被引：7
作者：
Alajarin, Mateo [1 ]
Berna, Jose [1 ]
Lopez-Leonardo, Carmen [1 ]
Steed, Jonathan W. [2 ]
机构：
[1] Univ Murcia, Fac Quim, Dept Quim Organ, E-30100 Murcia, Spain
[2] Univ Durham, Dept Chem, Durham DH1 3LE, England
来源：
CHEMICAL COMMUNICATIONS | 2008年 / 20期
关键词：
D O I：
10.1039/b801299g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Macrobicyclic triphosphazides are able to reversibly exchange one of their tripodal components by means of a dynamic disassembly-reassembly process; surprisingly this strategy provides better yields of cage compounds than a direct tripod-tripod coupling.
引用
收藏
页码：2337 / 2339
页数：3
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