Transient multi pulse method for the determination of N2O -: Interaction with ZSM-5 type zeolites

被引:10
作者
Ates, A
Reitzmann, A
机构
[1] Univ Karlsruhe, Inst Chem Verfahrenstech, D-76128 Karlsruhe, Germany
[2] Cumhuriyet Univ, Dept Chem Engn, TR-58000 Sivas, Turkey
来源
REACTION KINETICS AND CATALYSIS LETTERS | 2005年 / 86卷 / 01期
关键词
nitrous oxide; zeolite; surface oxygen; transient method;
D O I
10.1007/s11144-005-0289-z
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Multipulse experiments reveal qualitative and quantitative, time-resolved information about the interaction of N2O with ZSM-5 type zeolites under conditions of catalytic applications, like the mechanism of N2O decomposition, amount and reactivity of an atomic surface oxygen species.
引用
收藏
页码:11 / 20
页数:10
相关论文
共 17 条
  • [1] Evolution of iron states and formation of α-sites upon activation of FeZSM-5 zeolites
    Dubkov, KA
    Ovanesyan, NS
    Shteinman, AA
    Starokon, EV
    Panov, GI
    [J]. JOURNAL OF CATALYSIS, 2002, 207 (02) : 341 - 352
  • [2] Effect of high-temperature treatment on Fe/ZSM-5 prepared by chemical vapor deposition of FeCl3I.: Physicochemical characterization
    Hensen, EJM
    Zhu, Q
    Hendrix, MMRM
    Overweg, AR
    Kooyman, PJ
    Sychev, MV
    van Santen, RA
    [J]. JOURNAL OF CATALYSIS, 2004, 221 (02) : 560 - 574
  • [3] Identification by isotopic exchange of oxygen deposited on Fe/MFI by decomposing N2O
    Jia, JF
    Wen, B
    Sachtler, WMH
    [J]. JOURNAL OF CATALYSIS, 2002, 210 (02) : 453 - 459
  • [4] Kapteijn F, 1996, APPL CATAL B-ENVIRON, V9, P25
  • [5] Active sites in HZSM-5 with low Fe content for the formation of surface oxygen by decomposing N2O:: is every deposited oxygen active?
    Kiwi-Minsker, L
    Bulushev, DA
    Renken, A
    [J]. JOURNAL OF CATALYSIS, 2003, 219 (02) : 273 - 285
  • [6] Simultaneous catalytic removal of NO and N2O using Fe-MFI
    Kögel, M
    Mönnig, R
    Schwieger, W
    Tissler, A
    Turek, T
    [J]. JOURNAL OF CATALYSIS, 1999, 182 (02) : 470 - 478
  • [7] Kogel M., 2001, CATAL COMMUN, V2, P273, DOI DOI 10.1016/S1566-7367(01)00046-2
  • [8] KOWALAK S, 1999, P 12 INT ZEOL C MAT, V4, P1240
  • [9] PANOV GI, 1990, J MOL CATAL, V61, P85
  • [10] Generation of active oxygen species on solid surfaces. Opportunity for novel oxidation technologies over zeolites
    Panov, GI
    Uriarte, AK
    Rodkin, MA
    Sobolev, VI
    [J]. CATALYSIS TODAY, 1998, 41 (04) : 365 - 385