Construction of C1-symmetric zirconium complexes by the design of new Salan ligands.: Coordination chemistry and preliminary polymerisation catalysis studies

被引：38

作者：

Cohen, Ad ^{[1
]}

Yeori, Adi ^{[1
]}

Kopilov, Jacob ^{[1
]}

Goldberg, Israel ^{[1
]}

Kol, Moshe ^{[1
]}

机构：

[1] Raymond & Beverly Sackler Fac Exact Sci, Sch Chem, IL-69978 Tel Aviv, Israel

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 18期

关键词：

D O I：

10.1039/b719834e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first synthesis of achiral and chiral [ONNO']-type Salan ligands featuring two different phenol arms, and the diastereo-selective formation of the corresponding octahedral C-1-symmetric zirconium complexes is described; the activity and isospecificity induction of the [ONNO']Zr(bn)(2) complexes in 1-hexene polymerisation reflected those of the parent symmetric compounds.

引用

页码：2149 / 2151

页数：3

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