Ferromagnetic coupling between an alkoxo-bridged dinickel(II) pair in a mixed-spin tetranuclear nickel(II) complex

被引：15
|
作者：
Mikuriya, M [1 ]
Minowa, K [1 ]
Nagao, N [1 ]
机构：
[1] Kwansei Gakuin Univ, Sch Sci, Dept Chem, Nishinomiya, Hyogo 6628501, Japan
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2001年 / 4卷 / 08期
关键词：
nickel complex; tetranuclear complex; Schiff-base; magnetic property;
D O I：
10.1016/S1387-7003(01)00239-8
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A nickel(II) complex with 2-hydroxy-N.N ' -bis(1-methyl-3-hydroxy-3-phenyl-7-phenyl-2propen-1-ylidene)-1,3-propanediamine (H3L), [Ni-4(L)(2)(CH3O)(2)(CH3OH)(2)], was synthesized and structurally characterized. The X-ray crystal structure shows that the compound has a tetranuclear structure with a mixed-spin state consisting of octahedral NO5 and planar NO3 coordination environments, which is formed by alkoxo-bridges. Magnetic susceptibility data show ferromagnetic behavior. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：441 / 443
页数：3
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