Ferromagnetic coupling between an alkoxo-bridged dinickel(II) pair in a mixed-spin tetranuclear nickel(II) complex

被引：15

作者：

Mikuriya, M ^{[1
]}

Minowa, K ^{[1
]}

Nagao, N ^{[1
]}

机构：

[1] Kwansei Gakuin Univ, Sch Sci, Dept Chem, Nishinomiya, Hyogo 6628501, Japan

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2001年 / 4卷 / 08期

关键词：

nickel complex; tetranuclear complex; Schiff-base; magnetic property;

D O I：

10.1016/S1387-7003(01)00239-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A nickel(II) complex with 2-hydroxy-N.N ' -bis(1-methyl-3-hydroxy-3-phenyl-7-phenyl-2propen-1-ylidene)-1,3-propanediamine (H3L), [Ni-4(L)(2)(CH3O)(2)(CH3OH)(2)], was synthesized and structurally characterized. The X-ray crystal structure shows that the compound has a tetranuclear structure with a mixed-spin state consisting of octahedral NO5 and planar NO3 coordination environments, which is formed by alkoxo-bridges. Magnetic susceptibility data show ferromagnetic behavior. (C) 2001 Elsevier Science B.V. All rights reserved.

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页码：441 / 443

页数：3

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