Glycerol acetylation on sulphated zirconia in mild conditions

被引：69

作者：

Dosuna-Rodriguez, I. ^{[1
]}

Adriany, C. ^{[1
]}

Gaigneaux, E. M. ^{[1
]}

机构：

[1] Catholic Univ Louvain, IMCN, Div MOl Solids & React MOST, B-1348 Louvain, Belgium

来源：

CATALYSIS TODAY | 2011年 / 167卷 / 01期

关键词：

SO42-/ZrO2; Glycerol; Esterification; Acetic acid; SOLID ACID CATALYSTS; ESTERIFICATION; TRANSESTERIFICATION; OIL; SILICA; ALKYL;

D O I：

10.1016/j.cattod.2010.11.057

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

This work focuses on the role of the hydrolysis ratio over the physicochemical properties of sulphated zirconia (SZ) obtained by the sol-gel method. The solids obtained were tested in the esterification of acetic acid diluted in glycerol, the latter being used both as reactant and solvent. The acidic properties of the SZ samples and their performances in the acetylation reaction have been successfully correlated. The recyclability has also been studied: sample SZ-1 (sulphated zirconia prepared with a hydrolysis molar ratio = 1) shows a progressive deactivation in successive tests due to sulphur leaching which induces an activity in the homogeneous phase. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：56 / 63

页数：8

共 36 条

[21] Esterification of propanoic acid with ethanol, 1-propanol and butanol over a heterogeneous fiber catalyst
Lilja, J
Wärnå, J
Salmi, T
Pettersson, LJ
Ahlkvist, J
Grénman, H
Rönnholm, M
Murzin, DY
[J]. CHEMICAL ENGINEERING JOURNAL, 2005, 115 (1-2) : 1 - 12
[22] LOPERA JAM, 2002, THESIS U CATHOLIQUE
[23] Esterification and transesterification using modified-zirconia catalysts
Lopez, Dora E.
Goodwin, James G., Jr.
Bruce, David A.
Furuta, Satoshi
[J]. APPLIED CATALYSIS A-GENERAL, 2008, 339 (01) : 76 - 83
[24] Glycerol transformations on polysaccharide derived mesoporous materials
Luque, Rafael
Budarin, Vitaly
Clark, James H.
Macquarrie, Duncan J.
[J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2008, 82 (3-4) : 157 - 162
[25] Biodiesel production: a review
Ma, FR
Hanna, MA
[J]. BIORESOURCE TECHNOLOGY, 1999, 70 (01) : 1 - 15
[26] McCormick R, 2005, NRELTP54038836
[27] Sulphated zirconia by sol-gel route. The effects of the preparative variables
Melada, S
Ardizzone, SA
Bianchi, CL
[J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2004, 73 (03) : 203 - 209
[28] Acidic mesoporous silica for the acetylation of glycerol: Synthesis of bioadditives to petrol fuel
Melero, Juan A.
van Grieken, Rafael
Morales, Gabriel
Paniagua, Marta
[J]. ENERGY & FUELS, 2007, 21 (03) : 1782 - 1791
[29] Esterification of free fatty acids in sunflower oil over solid acid catalysts using batch and fixed bed-reactors
Ni, J.
Meunier, F. C.
[J]. APPLIED CATALYSIS A-GENERAL, 2007, 333 (01) : 122 - 130
[30] NOUREDDINI H, 1998, CHEM BIOMOL ENG RES, P232

← 1 2 3 4 →