Isotope ratio mass spectrometry:: δ13C and δ15 N analysis for tracing the origin of illicit drugs

被引：26
作者：
Galimov, EM [1 ]
Sevastyanov, VS [1 ]
Kulbachevskaya, EV [1 ]
Golyavin, AA [1 ]
机构：
[1] Russian Acad Sci, Vernadsky Inst Geochem & Analyt Chem, Moscow 119991, Russia
来源：
RAPID COMMUNICATIONS IN MASS SPECTROMETRY | 2005年 / 19卷 / 10期
关键词：
D O I：
10.1002/rcm.1896
中图分类号：
Q5 [生物化学];
学科分类号：
071010 ; 081704 ;
摘要：
Gas chromatography/combustion/mass spectrometry (GC-C-MS) and elemental analysis/mass spectrometry (EA-MS) techniques are proposed to estimate delta(13)C and delta(15)N values in heroin, morphine, cocaine and hemp leaves, for the purposes of tracing the geographical origins of seized drugs. The values of isotope ratios for pure drugs and drugs with impurities were compared. It was demonstrated that large samples (up to 3 X 10(-6) g C) were combusted completely, so that the results obtained were valid. The data are considered to be an essential supplement to a wide-scale database designed specifically for the delta(13)C and delta(15)N values of drugs. The potential forensic and academic significance of the results is discussed. Copyright (c) 2005 John Wiley & Sons, Ltd.
引用
收藏
页码：1213 / 1216
页数：4
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