Alkali metal-templated assembly of the tetrahedral cyanometallate cages [M⊂Mo4(μ-CN)6(CO)12]5- (M = Li, Na)

被引：27
作者：
Contakes, SM [1 ]
Rauchfuss, TB [1 ]
机构：
[1] Univ Illinois, Dept Chem, Urbana, IL 61801 USA
来源：
CHEMICAL COMMUNICATIONS | 2001年 / 06期
关键词：
D O I：
10.1039/b010192n
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Acetonitrile solutions of (mesitylene)Mo(CO)(3), 1.5 equiv. Et4NCN, and 0.25 equiv M+ afford the inorganic tetrahedranes (Et4N)(5)[M subset of Mo-4(mu -CN)(6)(CO)(12)] (M = Na, Li), the strained nature of which is indicated by their ready reaction with CsO3SCF3 to give trigonal prismatic (Et4N)(8)[Cs subset of Mo-6(mu -CN)(9)(CO)(18)].
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页码：553 / 554
页数：2
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