Heterometallic bismuth-transition metal homoleptic β-diketonates

被引：59
作者：
Dikarev, EV [1 ]
Zhang, H [1 ]
Li, B [1 ]
机构：
[1] Univ Albany, Dept Chem, Albany, NY 12222 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 17期
关键词：
D O I：
10.1021/ja051265m
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Bismuth(III) hexafluoroacetylacetonate reacts readily with the first row transition-metal species to produce trinuclear heterobimetallic coordination complexes Bi2M(β-diketonate)8 (M = Mn, Fe, Co, Ni, Cu, Zn). This unique, general approach may offer new possibilities for developing single-source molecular precursors for advance oxide materials. Copyright © 2005 American Chemical Society.
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页码：6156 / 6157
页数：2
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