Heterometallic bismuth-transition metal homoleptic β-diketonates

被引:59
作者
Dikarev, EV [1 ]
Zhang, H [1 ]
Li, B [1 ]
机构
[1] Univ Albany, Dept Chem, Albany, NY 12222 USA
关键词
D O I
10.1021/ja051265m
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Bismuth(III) hexafluoroacetylacetonate reacts readily with the first row transition-metal species to produce trinuclear heterobimetallic coordination complexes Bi2M(β-diketonate)8 (M = Mn, Fe, Co, Ni, Cu, Zn). This unique, general approach may offer new possibilities for developing single-source molecular precursors for advance oxide materials. Copyright © 2005 American Chemical Society.
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页码:6156 / 6157
页数:2
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