Diastereoselective tricyclization/dimerization of yne-indoles catalyzed by a Au(III) complex featuring an L2/Z-type ligand

被引：4

作者：

Murakami, Ryo ^{[1
]}

Tanishima, Hiroto ^{[1
]}

Naito, Daisuke ^{[1
]}

Kawamitsu, Hikari ^{[1
]}

Kamo, Ryoya ^{[1
]}

Uchida, Ayaka ^{[1
]}

Kawasaki, Kazuki ^{[1
]}

Kiyohara, Chihiro ^{[1
]}

Matsuo, Motoki ^{[2
]}

Maeda, Kakeru ^{[2
]}

Inagaki, Fuyuhiko ^{[1
]}

机构：

[1] Kobe Gakuin Univ, Fac Pharmaceut Sci, Chuo Ku, 1-1-3 Minatojima, Kobe, Hyogo 6508586, Japan

[2] Kanazawa Univ, Grad Sch Med Sci, Div Pharmaceut Sci, Kanazawa, Ishikawa 9201192, Japan

来源：

TETRAHEDRON LETTERS | 2021年 / 78卷

关键词：

DATIVE SIGMA-BOND; GOLD CATALYSIS; 8-MEMBERED RINGS; HYDROAMINATION; REACTIVITY; CYCLOISOMERIZATION; HYDROARYLATION; CONSTRUCTION; DERIVATIVES; CYCLIZATION;

D O I：

10.1016/j.tetlet.2021.153267

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In order to investigate catalyst activation via a (Au -> B)(8) interaction, Au(DPB)X-3 (DPB = diphosphine-borane) featuring an L-2/Z ligand was synthesized. The resulting cationic catalyst was utilized for the unprecedented diastereoselective tricyclization/dimerization of yne-indoles. (C) 2021 Elsevier Ltd. All rights reserved.

引用

页数：6

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