Nitro Lignin-Derived Nitrogen-Doped Carbon as an Efficient and Sustainable Electrocatalyst for Oxygen Reduction

被引：167

作者：

Graglia, Micaela ^{[1
]}

Pampel, Jonas ^{[1
]}

Hantke, Tina ^{[1
]}

Fellinger, Tim-Patrick ^{[1
]}

Esposito, Davide ^{[1
]}

机构：

[1] Max Planck Inst Colloids & Interfaces, D-14424 Potsdam, Germany

来源：

ACS NANO | 2016年 / 10卷 / 04期

关键词：

electrocatalysis; lignin; nitration; nitrogen-doped carbon; ionothermal carbonization; MESOPOROUS CARBONS; POROUS CARBONS; BIOMASS; NITRATION; VALORIZATION; PERFORMANCE;

D O I：

10.1021/acsnano.5b08040

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of lignin as a precursor for the synthesis of materials is nowadays considered very interesting from a sustainability standpoint. Here we illustrate the synthesis of a micro-, meso-, and macroporous nitrogen-doped carbon (NDC) using lignin extracted from beech wood via alkaline hydrothermal treatment and successively functionalized via aromatic nitration. The so obtained material is thus carbonized in the eutectic salt melt KCl/ZnCl2. The final NDC shows an excellent activity as electrocatalyst for the oxygen reduction reaction.

引用

页码：4364 / 4371

页数：8

共 39 条

[1] Isolation of high quality lignin as a by-product from ammonia percolation pretreatment of poplar wood [J].

Bouxin, Florent P. ;

Jackson, S. David ;

Jarvis, Michael C. .

BIORESOURCE TECHNOLOGY, 2014, 162 :236-242

[2] Deconstruction of lignocellulosic biomass with ionic liquids [J].

Brandt, Agnieszka ;

Grasvik, John ;

Hallett, Jason P. ;

Welton, Tom .

GREEN CHEMISTRY, 2013, 15 (03) :550-583

[3] Preparation and adsorption properties of activated porous carbons obtained using volatile zinc templating phases [J].

Cesano, Federico ;

Rahman, Mohammed Mastabur ;

Bertarione, Serena ;

Vitillo, Jenny G. ;

Scarano, Domenica ;

Zecchina, Adriano .

CARBON, 2012, 50 (05) :2047-2051

[4] Valorization of lignin waste from hydrothermal treatment of biomass: towards porous carbonaceous composites for continuous hydrogenation [J].

Chieffi, Gianpaolo ;

Fechler, Nina ;

Esposito, Davide .

RSC ADVANCES, 2015, 5 (78) :63691-63696

[5] Lignin - a useful bioresource for the production of sorption-active materials [J].

Dizhbite, T ;

Zakis, G ;

Kizima, A ;

Lazareva, E ;

Rossinskaya, G ;

Jurkjane, V ;

Telysheva, G ;

Viesturs, U .

BIORESOURCE TECHNOLOGY, 1999, 67 (03) :221-228

[6] Nitrogen-Doped Carbon Electrodes: Influence of Microstructure and Nitrogen Configuration on the Electrical Conductivity of Carbonized Polyacrylonitrile and Poly(ionic liquid) Blends [J].

Einert, Marcus ;

Wessel, Claas ;

Badaczewski, Felix ;

Leichtweiss, Thomas ;

Eufinger, Christine ;

Janek, Juergen ;

Yuan, Jiayin ;

Antonietti, Markus ;

Smarsly, Bernd M. .

MACROMOLECULAR CHEMISTRY AND PHYSICS, 2015, 216 (19) :1930-1944

[7] Metal-free ionic liquid-derived electrocatalyst for high-performance oxygen reduction in acidic and alkaline electrolytes [J].

Elumeeva, K. ;

Fechler, N. ;

Fellinger, T. P. ;

Antonietti, M. .

MATERIALS HORIZONS, 2014, 1 (06) :588-594

[8] High Surface Iron/Cobalt-Containing Nitrogen-Doped Carbon Aerogels as Non-Precious Advanced Electrocatalysts for Oxygen Reduction [J].

Elumeeva, Karina ;

Ren, Jiawen ;

Antonietti, Markus ;

Fellinger, Tim-Patrick .

CHEMELECTROCHEM, 2015, 2 (04) :584-591

[9] Chemical Conversion of Sugars to Lactic Acid by Alkaline Hydrothermal Processes [J].

Esposito, Davide ;

Antonietti, Markus .

CHEMSUSCHEM, 2013, 6 (06) :989-992

[10] "Salt Templating": A Simple and Sustainable Pathway toward Highly Porous Functional Carbons from Ionic Liquids [J].

Fechler, Nina ;

Fellinger, Tim-Patrick ;

Antonietti, Markus .

ADVANCED MATERIALS, 2013, 25 (01) :75-79

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