Synthesis and structure of [C2H10N2][B5O8(OH)]:: A nonmetal pentaborate with nonlinear optical properties

被引：56

作者：

Yang, Sihai ^{[1
]}

Li, Guobao ^{[1
]}

Tian, Shujian ^{[1
]}

Liao, Fuhui ^{[1
]}

Lin, Jianhua ^{[1
]}

机构：

[1] Peking Univ, BNLMS, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2007年 / 7卷 / 07期

关键词：

D O I：

10.1021/cg0606794

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A nonmetal pentaborate [C2H10N2][B5O8(OH)] (I) was synthesized by a solvothermal method at 150 degrees C and characterized by elemental analysis, IR, thermogravimetric analysis, and X-ray diffraction. The structure of I was determined by a single-crystal technique. It crystallizes in the monoclinic system with space group Cc, a = 6.7085 (13) angstrom, b = 11.437(2) angstrom, c = 12.530(3) angstrom, and beta = 95.41(3)degrees. Powder second-harmonic generation (SHG) efficiency measurements with Nd:YAG laser (1064 nm) radiation show that [C2H10N2][B5O8(OH)] has a SHG efficiency approximately 1.2 times of that of potassium dihydrogen phosphate (KDP).

引用

页码：1246 / 1250

页数：5

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