Oxidation of organoselenium compounds. A study of chemoselectivity of phenylacetone monooxygenase

被引：14

作者：

Andrade, Leandro H. ^{[1
]}

Pedrozo, Eliane C. ^{[1
]}

Leite, Henrique G. ^{[1
]}

Brondani, Patricia B. ^{[1
]}

机构：

[1] Univ Sao Paulo, Inst Quim, BR-05508900 Sao Paulo, Brazil

来源：

JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC | 2011年 / 73卷 / 1-4期

基金：

巴西圣保罗研究基金会;

关键词：

Selenium; Phenylacetone monooxygenase; Chemoselectivity; Selenoxide; BAEYER-VILLIGER MONOOXYGENASES; ORGANIC SELENIDES; ALLYLIC ALCOHOLS; CYCLOHEXANONE MONOOXYGENASE; ABSOLUTE-CONFIGURATION; SYNTHETIC APPLICATIONS; WHOLE CELLS; SELENOXIDES; BIOCATALYSTS; CONVERSION;

D O I：

10.1016/j.molcatb.2011.07.018

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Organoselenium acetophenones oxidation using enzymatic reactions has been developed and chemoselectivity of phenylacetone monooxygenase (PAMO) with selenium-containing ketones has been explored. We discovered that this biocatalyst prefers selenium oxidation, which leads to selenoxide in excellent conversion, over Baeyer-Villiger oxidation. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：63 / 66

页数：4

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