Promoting catalytic performances of Ni-Mn spinel for NH3-SCR by treatment with SO2 and H2O

被引：70
作者：
Chen, Liqiang [1 ,2 ]
Niu, Xiaoyu [1 ]
Li, Zhibin [1 ]
Dong, Yongli [1 ]
Zhang, Zhiping [1 ]
Yuan, Fulong [1 ]
Zhu, Yujun [1 ]
机构：
[1] Heilongjiang Univ, Minist Educ, Sch Chem & Mat, Key Lab Funct Inorgan Mat Chem, Harbin 150080, Peoples R China
[2] Heihe Univ, Sch Sci, Heihe 164300, Peoples R China
来源：
CATALYSIS COMMUNICATIONS | 2016年 / 85卷
关键词：
Ni-Mn spinel oxides; NH3-SCR; SO2 and H2O resistance; LOW-TEMPERATURE SCR; NO REDUCTION; MN-CE/TIO2; CATALYST; OXIDE CATALYSTS; NH3; MNOX/TIO2; CHROMIUM; CERIA; TIO2;
D O I：
10.1016/j.catcom.2016.07.013
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Ni(0.4)-MnOx catalyst was prepared by citrate combustion, which showed high catalytic performance for NH3-SCR reaction. After the resistance tests of SO2 and H2O, Ni(0.4)-MnOx-SH showed better NH3-SCR activity than that of Ni(0.4)-MnOx, when the temperature was >240 degrees C. The characterizations suggest that Ni(0.4)-MnOx-SH has more acid sites for ammonia adsorption and far weaker oxidation capacity for NH3, which resulted in the high catalytic activity at middle-temperature. (C) 2016 Published by Elsevier B.V.
引用
收藏
页码：48 / 51
页数：4
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