A facile and rapid route to synthesize CuOx/Ce0.8Zr0.2O2 catalysts with high performance for CO preferential oxidation (CO-PROX)

被引：30
|
作者：
Wang, Jing [1 ]
Deng, Lian [1 ,2 ]
He, Dedong [1 ]
Lu, Jichang [1 ]
He, Suyun [1 ]
He, Sufang [3 ]
Luo, Yongming [1 ]
机构：
[1] Kunming Univ Sci & Technol, Fac Environm Sci & Engn, Kunming 650500, Peoples R China
[2] Guangzhou Res Inst Environm Protect, Guangzhou 510620, Guangdong, Peoples R China
[3] Kunming Univ Sci & Technol, Res Ctr Anal & Measurement, Kunming 650093, Peoples R China
来源：
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2015年 / 40卷 / 36期
基金：
中国国家自然科学基金;
关键词：
CO-PROX; CuO-Ce0.8Zr0.2O2; Synthesis method; MIXED-OXIDE CATALYSTS; SELECTIVE OXIDATION; CARBON-MONOXIDE; CUO-CEO2; CATALYSTS; EXCESS HYDROGEN; METAL; AU/ALPHA-FE2O3; CE0.8ZR0.2O2; METHANE; GAS;
D O I：
10.1016/j.ijhydene.2015.07.063
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
CuO(10)-Ce0.8Zr0.2O2-UGC-300 (CuO-Ce0.8Zr0.2O2 prepared by urea grind combustion method, with 10 wt.% CuO loading and calcined at 300 degrees C) and CuO(10)-Ce0.8Zr0.2O2-IWI-300 (prepared by incipient wetness impregnation method) catalysts were tested for CO-PROX. It was noticed that both the CO conversion and the O-2 selectivity of CuO(10)-Ce0.8Zr0.2O2-UGC-300 are higher than those of CuO(10)-Ce0.8Zr0.2O2-IWI-300. The high performance catalytic activities of CuO(10)-Ce0.8Zr0.2O2-UGC-300 have been attributed to the synergistic effects of highly dispersed Cu species together with the stronger interaction between CuO and the support. The effect of the CuO content and calcination temperature on the catalytic activity of the CuO-Ce0.8Zr0.2O2 catalysts were investigated in detail. The catalyst with 10 wt.% CuO loading and calcined at 300 degrees C exhibited the highest catalytic activity. CuO(10)-Ce0.8Zr0.2O2-UGC-300 catalyst exhibited excellent adaptability of space velocity from 12,000 h(-1) to 36,000 h(-1) and with good tolerance towards CO2 and H2O. Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：12478 / 12488
页数：11
相关论文
共 50 条
  • [21] Formaldehyde Oxidation of Ce0.8Zr0.2O2 Nanocatalysts for Room Temperature: Kinetics and Effect of pH Value
    Yang, Zonglin
    Qin, Gaoyuan
    Tang, Ruijiu
    Jia, Lijuan
    Wang, Fang
    Liu, Tiancheng
    NANOMATERIALS, 2023, 13 (14)
  • [22] Synthesis of high-performance Ni/Ce0.8Zr0.2O2 catalyst via co-nanocasting method for ethanol dry reforming
    Shi, Guangyu
    Wang, Yuanhao
    Cao, Yafeng
    Cai, Weijie
    Tan, Fengzhi
    KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2020, 37 (12) : 2143 - 2151
  • [23] Elucidating the structure, redox properties and active entities of high-temperature thermally aged CuOx-CeO2 catalysts for CO-PROX
    Qiu, Zhihuan
    Guo, Xiaolin
    Mao, Jianxin
    Zhou, Renxian
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2021, 23 (29) : 15582 - 15590
  • [24] Preparation of mesoporous nanocrystalline CuO-ZnO-Al2O3 catalysts for the H2 purification using catalytic preferential oxidation of CO (CO-PROX)
    Andache, Mahmood
    Kharat, Ali Nemati
    Rezaei, Mehran
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2019, 44 (50) : 27401 - 27411
  • [25] Boosting the active sites of Cu/Ce0.8Zr0.2O2 catalysts through tailored precipitation method
    Ahn, Seon-Yong
    Han, Jong-Hoon
    Roh, Hyun-Seog
    CHEMICAL ENGINEERING JOURNAL, 2024, 499
  • [26] Hydrogen interaction with Pd/Ce0.8Zr0.2O2 nanocomposites prepared by microemulsion, coprecipitation and supercritical CO2 treatment
    Gennari, F. C.
    Carbajal Ramos, A.
    Condo, A.
    Montini, T.
    Bengio, S.
    Cortesi, A.
    Andrade Gamboa, J. J.
    Fornasiero, P.
    APPLIED CATALYSIS A-GENERAL, 2011, 398 (1-2) : 123 - 133
  • [27] Superior performance of gold supported on doped CeO2 catalysts for the preferential CO oxidation (PROX)
    de Oliveira Jardim, Erika
    Rico-Frances, Soledad
    Coloma, Fernando
    Ramos-Fernandez, Enrique V.
    Silvestre-Albero, Joaquin
    Sepulveda-Escribano, Antonio
    APPLIED CATALYSIS A-GENERAL, 2014, 487 : 119 - 129
  • [28] Rapid synthesis of Fe-doped CuO-Ce0.8Zro0.2O2 catalysts for CO preferential oxidation in H2-rich streams: Effect of iron source and the ratio of Fe/Cu
    Wang, Jing
    Han, Caiyun
    Gao, Xiaoya
    Lu, Jichang
    Wan, Gengpin
    He, Dedong
    Chen, Ran
    Chen, Kezhen
    He, Sufang
    Luo, Yongming
    JOURNAL OF POWER SOURCES, 2017, 343 : 437 - 445
  • [29] High-surface-area Ce0.8Zr0.2O2 solid solutions supported Ni catalysts for ammonia decomposition to hydrogen
    Deng, Qing-Fang
    Zhang, Hui
    Hou, Xiao-Xu
    Ren, Tie-Zhen
    Yuan, Zhong-Yong
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2012, 37 (21) : 15901 - 15907
  • [30] CO2 Methanation over Rare Earth Doped Ni-Based Mesoporous Ce0.8Zr0.2O2 with Enhanced Low-Temperature Activity
    Yang, Zhenglong
    Cui, Yan
    Ge, Pengxiang
    Chen, Mindong
    Xu, Leilei
    CATALYSTS, 2021, 11 (04)
12345