Synthesis, Characterization, and Heterogeneous Catalytic Activity of Sulfamic Acid Functionalized Magnetic IRMOF-3

被引：13

作者：

Mostafavi, Mohammad Mahdi ^{[1
]}

Movahedi, Farnaz ^{[1
]}

机构：

[1] Standard Res Inst, Dept Chem & Petrochem Engn, POB 31745-139, Karaj, Iran

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2019年 / 2019卷 / 06期

关键词：

Magnetic metal-organic framework; Functionalized IRMOF-3; Nanocomposite catalyst; Multicomponent reactions; Heterogeneous catalysis; METAL-ORGANIC FRAMEWORKS; EFFICIENT ONE-POT; SULFONIC-ACID; SOLVENT-FREE; PHARMACOLOGICAL EVALUATION; MULTICOMPONENT REACTIONS; PYRIMIDINE-DERIVATIVES; MESOPOROUS SBA-15; NANOPARTICLES; NANOCATALYST;

D O I：

10.1002/ejic.201801054

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this work, post-synthesis modification of Fe3O4/IRMOF-3 nanocomposite with chlorosulfonic acid groups afforded sulfamic acid-functionalized magnetic metal-organic frameworks (Fe3O4/IRMOF-3/SO3H). Functionalization was followed through FT-IR, XRD, TGA, BET, FESEM/EDS and elemental analysis. The catalytic efficiency of the as-prepared nanocomposite was evaluated through one-pot pseudo four-component reaction of secondary amines, malononitrile, and salicylaldehyde in EtOH under mild conditions. The magnetic tendency of the functionalized IRMOF-3 enabled simple decantation from the reaction mixture with use of an external magnetic field, with subsequent catalyst reuse for at least five times without significant loss of catalytic efficiency.

引用

页码：787 / 793

页数：7

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